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Difference Between Chlorinated Polypropylene Resin and Chlorinated Polyolefin Resin

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Difference Between Chlorinated Polypropylene Resin and Chlorinated Polyolefin Resin

2025-08-20

Chlorinated Polypropylene Resin (CPP) and Chlorinated Polyolefin Resin (CPO) are similar in name and application, but they have a container-contained relationship. Simply put, Chlorinated Polypropylene is a type of Chlorinated Polyolefin.

Core Relationship: Inclusion

Chlorinated Polyolefin is a broad category referring to all polyolefin resins that have undergone chlorination modification.

Chlorinated Polypropylene is a major subclass within the Chlorinated Polyolefin category, specifically referring to products made from polypropylene (PP) raw material through chlorination.

 

You can understand it like this:

Polyolefin (e.g., polyethylene PE, polypropylene PP) → Chlorination → Chlorinated Polyolefin (e.g., chlorinated polyethylene CPE, chlorinated polypropylene CPP)

Therefore, Chlorinated Polypropylene (CPP) is a type of Chlorinated Polyolefin (CPO).

Chlorinated Polypropylene supplier

Detailed Comparison

To help you understand more clearly, here is a comparison table contrasting the broad category of "Chlorinated Polyolefin" with the specific product "Chlorinated Polypropylene".

Property

Chlorinated Polypropylene

Chlorinated Polyolefin

Definition & Scope

Specifically refers to polymers made from polypropylene (PP) raw material through chlorination reaction.

Generally refers to a large category of polymers made from various polyolefins (e.g., polyethylene PE, polypropylene PP, EVA, etc.) through chlorination modification.

Main Types

It is a specific product type.

It is a product category, mainly including:
1. Chlorinated Polyethylene (CPE)
2. Chlorinated Polypropylene (CPP)
3. Chlorinated EVA
4. Other Chlorinated Polyolefins

Chlorine Content

Typically controlled between 20% - 40% depending on application, with significant performance differences between products with different chlorine content.

Wide range of chlorine content, from over 20% to over 70%, depending on the specific product and application. For example, CPE as a plastic modifier has about 35% chlorine content, while as an elastomer it can reach 40-45%.

Key Properties

1. Excellent adhesion, especially to polyolefin plastics like PP and PE that are difficult to adhere to.
2. Good compatibility, weather resistance, chemical resistance.
3. Good solubility, easily soluble in aromatic hydrocarbons, esters, ketones and other solvents.

Properties vary by specific type, very diverse:
• CPP: Strong adhesion (as above).
• CPE: Excellent impact modification ability, weather resistance, flame retardancy, and flexibility.

Main Applications

1. Coatings and Inks: Adhesion promoter and base resin for plastic coatings (e.g., PP automotive bumpers, appliance housings), which is its main use.
2. Adhesives: Used in adhesives for difficult-to-bond plastics (e.g., PP/PE).
3. Carrier Resin: Used in manufacturing color masterbatches.

Broader application areas, depending on the specific type:
1. CPP: Same as above.
2. CPE:
• Plastic Modification: Used as an impact modifier for PVC to improve toughness.
• Wires & Cables: Used as flame-retardant, weather-resistant sheathing material.
• Waterproof Membranes: Used in polymer waterproof membranes.
• Rubber blend modification.

Raw Material

Polypropylene (PP)

Various Polyolefins, such as:
• Polyethylene (PE) → Chlorinated Polyethylene (CPE)
• Polypropylene (PP) → Chlorinated Polypropylene (CPP)
• Ethylene-Vinyl Acetate Copolymer (EVA) → Chlorinated EVA

Summary & Analogy

Relationship

Chlorinated Polyolefin is like the broad category of "Fruit", while Chlorinated Polypropylene is like the specific type "Apple". Just as fruit includes apples, bananas, oranges, etc., similarly, chlorinated polyolefin includes chlorinated polyethylene, chlorinated polypropylene, etc.

Core Difference

When people say "Chlorinated Polyolefin", they usually might be referring to Chlorinated Polyethylene (CPE), as CPE is the most produced and widely used type of chlorinated polyolefin, especially in plastic modification and cable fields. When specifically saying "Chlorinated Polypropylene", it specifically refers to the type used for adhesion promotion.

Chlorinated Polyolefin supplier

 

If you need to solve the problem of coating, printing, or adhesion on polypropylene (PP) or polyethylene (PE) plastic surfaces, then you need Chlorinated Polypropylene (CPP) or its derivatives.
If you need to improve the toughness (impact resistance) of PVC materials or manufacture flame-retardant cables, waterproof materials, then you need Chlorinated Polyethylene (CPE).

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